aredness can take place national, provincial and hospital levels. Nursing professionals participate in hospital disaster preparedness and work with multidisciplinary teams to provide services. Nurses should be prepared for such participation, as their involvement, through tailored services for hospital disaster preparedness, can expand the literature on nursing knowledge to improve clinical outcomes.Polyoxometalates (POMs) have emerged as material of interest in many applications such as energy storage and conversion due to their redox activity and molecularly defined structure. However, especially for polyoxovanadates a lack of understanding between structural modifications and physicochemical properties remains. The present study leverages a lacunary dodecavanadate to systematically investigate the electronic effect of heterometal functionalization. While structural distortion affects the stability of the cluster, the redox potentials correlate with the overall cluster charge. Furthermore, we report the first bromide-templated analogue of this cluster family. Pralsetinib While the halide anion is crucial for the formation of the cluster, no major effect on the electrochemical properties is observed. By improving the understanding of structure-property relationship in this work, we hope to enable a more predictable tuning of redox-properties of polyoxovandates.

Pyridine-2,6-dicarboxamides (PDCAMs) exhibit a certain extraction ability for tetravalent actinide ions, but quite limited information is available regarding the structures and reactivities of corresponding An

-PDCAMs complexes. Neutral diamides can form multiply charged complexes with lanthanide and actinide cations, which are well suited for gas-phase investigations by using electrospray ionization mass spectrometry in conjunction with theoretical calculation.

Binary Th (TMPDCAM)

/U (TMPDCAM)

(TMPDCAM = N,N,N’,N’-tetramethylpyridine-2,6-dicarboxamide) complexes were generated in the gas phase via electrospray ionization (ESI) of Th (ClO

)

/U (ClO

)

and TMPDCAM mixtures in acetonitrile, collision-induced dissociation (CID) was employed to reveal their fragmentation behaviors, the structure and bonding were investigated by density functional theory (DFT) calculation.

An (TMPDCAM)

(An = Th and U) tetracations dominated the ESI mass spectra of An (ClO

)

and TMPDCAM mixtures inmistry of quadruply charged actinide-diamide complexes are affected by the metal centers with distinct properties.

An4+ (An = Th and U) can form stable tetrapositive complexes in the gas phase upon coordination of three neutral TMPDCAM ligands. Structure and bonding analyses indicate that the two An (TMPDCAM)3 4+ complexes possess twisted tricapped trigonal prismatic geometry, the An4+ centers are coordinated by six Ocarbonyl and three Npyridine atoms while the interactions between An4+ and Ocarbonyl is stronger. The fragmentation chemistry of Th (TMPDCAM)3 4+ and U (TMPDCAM)3 4+ is quite different from each other, which reveals that the gas-phase chemistry of quadruply charged actinide-diamide complexes are affected by the metal centers with distinct properties.For the past few years, a new generation of energy storage systems with large theoretical specific capacity has been urgently needed because of the rapid development of society. Lithium-sulfur (Li-S) batteries are regarded as one of the most promising candidates for novel battery systems, since their resurgence at the end of the 20th century Li-S batteries have attracted ever more attention, attributed to their notably high theoretical energy density of 2600 W h kg-1 , which is almost five times larger than that of commercial lithium-ion batteries (LIBs). One of the determining factors in Li-S batteries is how to design/prepare the sulfur cathode. For the sulfur host, the major technical challenge is avoiding the shuttling effect that is caused by soluble polysulfides during the reaction. In past decades, though the sulfur cathode has developed greatly, there are still some enormous challenges to be conquered, such as low utilization of S, rapid decay of capacity, and poor cycle life. This article spotlights the recent progress and foremost findings in improving the performance of Li-S batteries by employing multifunctional metal phosphides as host materials. The current state of development of the sulfur electrode of Li-S batteries is summarized by emphasizing the relationship between the essential properties of metal phosphide-based hybrid nanomaterials, the chemical reaction with lithium polysulfides and the latter’s influence on electrochemical performance. Finally, trends in the development and practical application of Li-S batteries are also pointed out.A series of expanded helicenes of different sizes and shapes incorporating phenyl- and biphenyl-substituents at the deepest part of their fjord have been synthesized via sequential Au-catalyzed hydroarylation of appropriately designed diynes, and their racemization barriers have been calculated employing electronic structure methods. These show that the overall profile of the inversions (energies, number of transition states and intermediates, and their relative position) is intensively affected by the interplay of steric and attractive London dispersion interactions. Hence, in-fjord substitution constitutes an additional tool to handle the mechanical properties in helicenes of uncommonly large diameter. The photochemical characterization of the newly prepared helical structures is also reported.Monitoring of herbicides and pesticides in water, food, and the environment is essential for human health, and this requires low-cost, portable devices for widespread deployment of this technology. For the first time, a wearable glove-based electrochemical sensor based on conductive Ag nano-ink was developed for the on-site monitoring of trifluralin residue on the surface of various substrates. Three electrode system with optimal thicknesses was designed directly on the finger surface of a rubber glove. Then, fabricated electrochemical sensor used for the direct detection of trifluralin in the range of 0.01 μM to 1 mM on the surface of tomato and mulberry leaves using square wave voltammetry (SWV) and difference pulse voltammetry technique. The obtained LLOQ was 0.01 μM, which indicates the suitable sensitivity of this sensor. On the other hand, this sensor is portable, easy to use, and has a high environmental capability that can be effective in detecting other chemical threats in the soil and water environment.