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By tuning the surface coverage of DNAzyme, the sensitivity and dynamic range could be controlled. This sensor also featured high selectivity to Pb2+ ions and simple detection procedure. Successful detection of Pb2+ ions in groundwater indicates that this method has the prospect in the onsite detection of Pb2+ ions in water. Given the variety of AuNPs and metal-specific DNAzymes, this detection strategy would lead to the development of more sensitive and versatile heavy metal sensors. Graphical abstract.Utilizing National High-tech Industrial Development Zones (NHIDZs) as a quasi-natural experiment, this study has adopted 285 prefecture and above cities from 2003 to 2018 in China as the research samples and constructed the difference-in-differences (DID) and spatial difference-in-differences (SDID) models to investigate the effects of NHIDZs on economic development and environmental pollution at national, regional, and administrative levels. The results show that NHIDZs have basically achieved a win-win situation in promoting economic development and reducing environmental pollution at the national level. However, spatial heterogeneity is supported at regional and administrative levels. GSK-3 inhibitor Specifically, “the law of diminishing marginal effect” of NHIDZs is proved in the eastern cities and key cities, which reveals the uneven development pattern of government leading in China, and highlights the importance and necessary of making policy according to local conditions and governing environmental pollution by classification.The soil microbiome comprises one of the most important and complex components of all terrestrial ecosystems as it harbors millions of microbes including bacteria, fungi, archaea, viruses, and protozoa. Together, these microbes and environmental factors contribute to shaping the soil microbiome, both spatially and temporally. Recent advances in genomic and metagenomic analyses have enabled a more comprehensive elucidation of the soil microbiome. However, most studies have described major modulators such as fungi and bacteria while overlooking other soil microbes. This review encompasses all known microbes that may exist in a particular soil microbiome by describing their occurrence, abundance, diversity, distribution, communication, and functions. Finally, we examined the role of several abiotic factors involved in the shaping of the soil microbiome.Trinexapac-ethyl (TE) was more widely used in golf course worldwide. As a plant growth regulator, it inhibited grass development and delayed grass cutting date. Direct contact with TE by workers that handle and apply these agents can lead to harmful effects depending on the exposure dosage and duration. Many studies have focused on the growth regulation of TE in plants, while its health risks to human beings were rarely reported. Here, we investigated the risk assessment of workers directly dermal exposed to TE by using some absorbent paper patches. The exposure intensity (EI) and potential dermal exposure (PDE) of worker body sections were obtained, and different exposure patterns were compared. The EI of each body section among mixing/loading, hand-held power sprayer, and manual sprayer workers was ranging from 7.22 to 73.0 pg cm-2. The maximum EI of TE was found on hands of manual sprayers, while the minimum EI of TE was recorded on upper arms of mixing and loading workers. The maximum contribution sections was 29% for the chest and back from mixing/loading workers, 40% for the chest and back from hand-held power sprayers, and 32% for the thigh from manual sprayers. The unit weight potential dermal exposure (UWPDE) of hand-held power sprayers was 60% lower than that of manual sprayers, indicating that hand-held power sprayers were safer than those of manual sprayers. These findings revealed that trinexapac-ethyl posed relatively higher exposure risks to manual sprayer workers than other operator workers in golf course, mainly responsible for body sections of the chest and back and thigh.In the present study, a magnetic adsorbent, rhein-coated magnetic Fe3O4 nanoparticle (RMNP), for Pb2+ and Mg2+ had been developed, and adsorption mechanism was studied via low-field NMR. RMNP was characterized by TEM, FTIR, and XRD. RMNP could adsorb and remove Pb2+ and Mg2+ from water and was successfully applied to remove Pb2+ and Mg2+ from wastewater, with satisfactory recovery rates and high adsorption capacities. The calculated maximum adsorption capacity for Mg2+ and Pb2+ was approximately 69.3 and 64.9 mg g-1 of RMNP, respectively, which was better than some results reported. Low-field NMR results showed that Pb2+ or Mg2+ enhanced the T2 relaxation time of RMNP, which suggested that RMNP selectively coordinated with Pb2+ or Mg2+ and led to the aggregation of RMNP, furthermore removal of Pb2+ or Mg2+ from water. The standard curves for △T2-cation concentration exhibited good line correlation. The linear ranges were from 4.2 × 10-6 to 2.0 × 10-4 mol L-1 for Pb2+ and from 5.0 × 10-6 mol L-1 to 1.0 × 10-4 mol L-1 for Mg2+, respectively. The limits of detection were 1.4 × 10-6 mol L-1 for Pb2+ and 2.1 × 10-6 mol L-1 for Mg2+, respectively. In short, low-field NMR could clearly display the interaction between RMNP and Pb2+ or Mg2+, even be used to detect Pb2+ or Mg2+ in suitable condition. Besides, this method could be expanded to study the interaction between other magnetic adsorbents and analytes.The purpose of the present study was to investigate the efficacy of the experimental formulations of the metribuzin (MET) and tribenuron-methyl (TBM) herbicides embedded in the matrix of degradable poly-3-hydroxybutyrate blended with wood flour in field-grown tomato and beet crops infested by weeds. There is a necessity to develop environmentally friendly and effective means to protect plants because of the shortcomings of the free herbicide forms such as the environmentally unsafe spray application of solutions and suspensions of the widespread metribuzin and tribenuron-methyl herbicides, removal from soil during watering events and rains, and transport to natural aquatic environments, where the herbicides accumulate in the trophic chains of biota. Free TBM is also rapidly inactivated in soil and metabolized to nontoxic products in plants. The efficacy of experimental formulations of metribuzin and tribenuron-methyl embedded in the matrix of degradable poly-3-hydroxybutyrate blended with wood flour was tested in field-grown tomato and beet crops infested with weeds.